Synthesis of cyclic diborenes with unprecedented cis-configuration.
نویسندگان
چکیده
The first examples of cis-configured diborenes - and the first cyclic diborenes - are isolated by taking advantage of stabilisation by chelating diphosphine ligands. The diborenes are prepared by a convenient one-pot reductive procedure that circumvents the need for a pre-formed base-adduct of the boron-containing precursor.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 88 شماره
صفحات -
تاریخ انتشار 2015